Cyclic Anion-Responsive π-Electronic Molecules That Overcome Energy Losses Induced by Conformation Changes

被引：13

作者：

Kaname, Shunsuke ^{[1
]}

Haketa, Yohei ^{[1
]}

Yasuda, Nobuhiro ^{[2
]}

Maeda, Hiromitsu ^{[1
]}

机构：

[1] Ritsumeikan Univ, Dept Appl Chem, Coll Life Sci, Kusatsu 5258577, Japan

[2] Japan Synchrotron Radiat Res Inst, Res & Utilizat Div, Sayo 6795198, Japan

来源：

ORGANIC LETTERS | 2018年 / 20卷 / 11期

关键词：

BF2; COMPLEXES; SUBSTITUTED DIPYRROLYLDIKETONES; RECEPTOR; DIFFRACTOMETRY;

D O I：

10.1021/acs.orglett.8b01138

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Preorganized structures suitable for anion binding were prepared by introducing dipyrrolyldiketone BF2 complexes as acyclic anion-responsive pi-electronic molecules into macrocycles. Pyrrole-inverted conformations, which typically present low stability in the case of acyclic derivatives, were obtained by covalent linkages through ring-closing olefin metathesis, exhibiting extremely high affinity for different anions.

引用

页码：3268 / 3272

页数：5

共 48 条

[21] Complexation of Anion-responsive π-Electronic System with Alkyl-substituted Azobenzene Carboxylate Providing Ion-pairing Assemblies
Yamakado, Ryohei
Hara, Mitsuo
Nagano, Shusaku
Seki, Takahiro
Maeda, Hiromitsu
CHEMISTRY LETTERS, 2018, 47 (04) : 404 - 407
[22] Dimension-controlled assemblies of anion-responsive π-electronic systems bearing aryl substituents with fan-shaped geometries
Lakshmi, Vellanki
Haketa, Yohei
Yamakado, Ryohei
Yasuda, Nobuhiro
Maeda, Hiromitsu
CHEMICAL COMMUNICATIONS, 2017, 53 (27) : 3834 - 3837
[23] Anion-Responsive Boron-Spiro-Centered p-Electronic Systems That Form Ion-Pairing Assemblies
Koda, Naoya
Haketa, Yohei
Yokoyama, Miyu
Yasuda, Nobuhiro
Maeda, Hiromitsu
ORGANIC LETTERS, 2023, 25 (07) : 1120 - 1125
[24] Ion-Free and Ion-Pairing Assemblies of Anion-Responsive -Electronic Systems Possessing Directly Linked Alkyl Chains
Haketa, Yohei
Katayama, Daisuke
Fukunaga, Shinya
Bando, Yuya
Sakurai, Tsuneaki
Matsuda, Wakana
Seki, Shu
Maeda, Hiromitsu
CHEMISTRY-AN ASIAN JOURNAL, 2016, 11 (14) : 2025 - 2029
[25] Electronic and Optical Properties in the Solid-State Molecular Assemblies of Anion-Responsive Pyrrole-Based it-Conjugated Systems
Maeda, Hiromitsu
Bando, Yuya
Haketa, Yohei
Honsho, Yoshihito
Seki, Shu
Nakajima, Hiromi
Tohnai, Norimitsu
CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (36) : 10994 - 11002
[26] Structure-Activity Relationships for Anion-Responsive Poly(squaramides): Support for an Analyte-Induced Noncovalent Polymer Cross-Linking Mechanism
Rostami, Ali
Guerin, Gerald
Taylor, Mark S.
MACROMOLECULES, 2013, 46 (16) : 6439 - 6450
[27] ENERGY OF THE PAIRWISE INTERACTIONS OF THE MOLECULES OF SOME LIQUID-CRYSTALS WITH CONSIDERATION OF THE CHANGES IN THEIR CONFORMATION
SARKISYAN, AT
YAILOYAN, SM
JOURNAL OF STRUCTURAL CHEMISTRY, 1991, 32 (01) : 75 - 78
[28] CHANGES IN THE CONFORMATION AND ELECTRONIC-STRUCTURE OF MOLECULES UPON PHASE-TRANSITIONS IN A UNIAXIAL LIQUID-CRYSTAL
AVERYANOV, EM
MINEEV, LI
JOURNAL OF STRUCTURAL CHEMISTRY, 1986, 27 (02) : 245 - 249
[29] Additive effects of electronic and nuclear energy losses in irradiation-induced amorphization of zircon
Zarkadoula, Eva
Toulemonde, Marcel
Weber, William J.
APPLIED PHYSICS LETTERS, 2015, 107 (26)
[30] LASER-INDUCED TRANSLATIONAL ENERGY CHANGES IN POLYATOMIC-MOLECULES
SIEBERT, DR
GRABINER, FR
FLYNN, GW
BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1973, 18 (04): : 575 - 575

← 1 2 3 4 5 →