Photochemistry and reaction intermediates of the bimetallic Group VIII cyclopentadienyl metal carbonyl compounds, (η5-C5H5)2M2(CO)4 and their derivatives

被引：81

作者：

Bitterwolf, TE ^{[1
]}

机构：

[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2000年 / 206卷

关键词：

photochemistry; reaction intermediates; group VIII; cyclopentadienyl metal carbonyl compounds;

D O I：

10.1016/S0010-8545(00)00251-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The bonding, structures and photochemistry of the Group VIII metal cyclopentadienyl carbonyl derivatives of the form, (eta(5)-C5H5)(2)M-2(CO)(4), where M = Fe, Ru and Os, are reviewed. The primary emphasis of the review is to bring together the somewhat complex literature in this field, to critically examine the evidence and interpretations and to identify areas for future research opportunities. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：419 / 450

页数：32

共 50 条

[21] Thermodynamics of the Metal-Hydrogen Bonds in (η5-C5H5)M(CO)2H (M = Fe, Ru, Os)
Estes, Deven P.
Vannucci, Aaron K.
Hall, Ariel R.
Lichtenberger, Dennis L.
Norton, Jack R.
ORGANOMETALLICS, 2011, 30 (12) : 3444 - 3447
[22] Synthesis and characteristics of novel pentanuclear complexes [(OC)3Mn(η1,η5-C5H4)Fe(CO)2(η1,η5-C5H4CO2)]2M(η5-C5H5)2 (M=Ti, Zr)
T. Yu. Orlova
Yu. S. Nekrasov
P. V. Petrovskii
M. G. Ezernitskaya
B. V. Lokshin
M. Kh. Minacheva
L. A. Strunkina
O. L. Lependina
T. V. Magdesieva
S. V. Milovanov
K. P. Butin
Russian Chemical Bulletin, 1997, 46 : 1018 - 1021
[23] NITROSYL COMPLEXES——SYNTHESIS, CHARACTERIZATION AND CRYSTAL STRUCTURES OF （η5-C5H5）M（CO）2NO AND （η5-C5H5）M（μ3-NH）(μ2-NO)（μ2-CO）Fe2（CO）6（M=Mo OR W）
杨世琰
孙文华
殷元骐
郁开北
周忠远
Science China Chemistry, 1991, (11) : 1304 - 1311
[24] Nature of M-(η2-H-SiR2) bonds in chromium, molybdenum and tungsten complexes [(η5-C5H5)(dmpe)M(η2-H-SiR2)] and [(η5-C5H5)(CO)2M(η2-H-SiMe2)]: A theoretical study
Pandey, Krishna K.
POLYHEDRON, 2013, 55 : 241 - 248
[25] Preparation and crystal structures of [μ-SbPh2]2[Mo(CO)2(η5-C5H5)]2•CHCl3, and SbPh[Fe(CO)2(η5-C5H5)]2
Gibbons, MN
Sowerby, DB
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 571 (02) : 289 - 295
[26] Reaction of Os2(CO)6(μ-η1,η1-C2H4) with (η5-C5H5)Rh(CO)PR3 (R = Me, Os2Rh(CO)8(η5-C5H5)PMe3
Organometallics, 2 (698):
[27] Experimental measure of metal-alkynyl electronic structure interactions by photoelectron spectroscopy: (η5-C5H5)Ru(CO)2CCMe and [(η5-C5H5)Ru(CO)2]2(μ-CC)
Head, Ashley R.
Renshaw, Sharon K.
Uplinger, Andrew B.
Lomprey, Jeffrey R.
Selegue, John P.
Lichtenberger, Dennis L.
POLYHEDRON, 2015, 86 : 141 - 150
[28] Synthesis of hexametallic CH2{(η5-C5H4)Fe(CO)2SnPh2(η5-C5H5)Fe(CO)2}2
McArdle, P
O'Neill, L
Cunningham, D
INORGANICA CHIMICA ACTA, 1999, 291 (1-2) : 252 - 257
[29] High-Pressure Study of Metallocenes, M(η5-C5H5)2 (M = Fe, Co)
Ovsyannikov, Sergey V.
Shchennikov, Vladimir V.
Titov, Alexander N.
Uwatoko, Yoshiya
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2007, 76 : 31 - 32
[30] Oxidative dehydrodimerization of rhenium vinylidene complex (η5-C5H5)(CO)2Re=C=C(H)Ph:: two competitive routes of coupling of σ-phenylethynyl intermediate [(η5-C5H5)(CO)2Re-C≡CPh]•.: X-ray structures of rhenium mononuclear (η5-C5H5)(CO)2Re=C=(H)Ph and binuclear [(η5-C5H5)(CO)2Re]2(μ2-C=C(Ph)C≡CPh) vinylidene compounds
Valyaev, DA
Semelkin, OV
Peterleitner, MG
Borisov, YA
Khrustalev, VN
Mazhuga, AM
Kremer, EV
Ustynyuk, NA
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (23) : 3837 - 3846

← 1 2 3 4 5 →