Synthesis and characteristics of novel pentanuclear complexes [(OC)3Mn(η1,η5-C5H4)Fe(CO)2(η1,η5-C5H4CO2)]2M(η5-C5H5)2 (M=Ti, Zr)

被引：0
|
作者：
T. Yu. Orlova
Yu. S. Nekrasov
P. V. Petrovskii
M. G. Ezernitskaya
B. V. Lokshin
M. Kh. Minacheva
L. A. Strunkina
O. L. Lependina
T. V. Magdesieva
S. V. Milovanov
K. P. Butin
机构：
[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds
[2] M. V. Lomonosov Moscow State University,Department of Chemistry
来源：
Russian Chemical Bulletin | 1997年 / 46卷
关键词：
Group IV metal, polynuclear complex, synthesis; IR spectra; electrochemistry;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The reaction of Cp2MCl2 complexes (M=Ti and Zr) with 2 equiv. of (OC)3Mn(η1,η5-C5H4)Fe(CO)2(η5-C5H4COONa) results in the formation of the pentanuclear complexes (OC)3Mn(η1,η5-C5H4)Fe(CO)2(η5-C5H4CO2)]2M(η5-C5H5)2, which are characterized by IR and1H NMR spectroscopy and cyclic voltammetry.
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页码：1018 / 1021
页数：3
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