Organotrifluoroborates and Monocoordinated Palladium Complexes as Catalysts-A Perfect Combination for Suzuki-Miyaura Coupling

被引：384
|
作者：
Molander, Gary A. [1 ]
Canturk, Belgin [1 ]
机构：
[1] Univ Penn, Dept Chem, Philadelphia, PA 19104 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 49期
基金：
美国国家卫生研究院;
关键词：
cross-coupling; N-heterocycliccarbenes; organotrifluoroborates; phosphines; Suzuki-Miyaura coupling; HETEROCYCLIC CARBENE LIGANDS; HIGHLY EFFICIENT CATALYST; HETEROARYL BORONIC ACIDS; HINDERED ARYL CHLORIDES; GENERATED IN-SITU; OXIDATIVE-ADDITION; ARYLBORONIC ACIDS; CROSS-COUPLINGS; CARBON-CARBON; C-N;
D O I：
10.1002/anie.200904306
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hitting the sweet spot: The combination of organotrifluoroborates and monocoordinated palladium complexes as catalysts in the Suzuki-Miyaura coupling reaction provides a powerful method for the creation of carbon-carbon bonds. The advantages of organotrifluoroborates include the numerous functional groups that are tolerated in the substrate, the mild reaction conditions, and the possibility to use different types of reagents. [Chemical Equation Presented]. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：9240 / 9261
页数：22
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