Organotrifluoroborates and Monocoordinated Palladium Complexes as Catalysts-A Perfect Combination for Suzuki-Miyaura Coupling

被引：384

作者：

Molander, Gary A. ^{[1
]}

Canturk, Belgin ^{[1
]}

机构：

[1] Univ Penn, Dept Chem, Philadelphia, PA 19104 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 49期

基金：

美国国家卫生研究院;

关键词：

cross-coupling; N-heterocycliccarbenes; organotrifluoroborates; phosphines; Suzuki-Miyaura coupling; HETEROCYCLIC CARBENE LIGANDS; HIGHLY EFFICIENT CATALYST; HETEROARYL BORONIC ACIDS; HINDERED ARYL CHLORIDES; GENERATED IN-SITU; OXIDATIVE-ADDITION; ARYLBORONIC ACIDS; CROSS-COUPLINGS; CARBON-CARBON; C-N;

D O I：

10.1002/anie.200904306

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hitting the sweet spot: The combination of organotrifluoroborates and monocoordinated palladium complexes as catalysts in the Suzuki-Miyaura coupling reaction provides a powerful method for the creation of carbon-carbon bonds. The advantages of organotrifluoroborates include the numerous functional groups that are tolerated in the substrate, the mild reaction conditions, and the possibility to use different types of reagents. [Chemical Equation Presented]. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9240 / 9261

页数：22

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