Iron-Catalyzed Oxidative Radical Alkoxycarbonylation of Activated Alkenes with Carbazates toward Alkoxycarbonylated Benzimidazo[2,1-a]isoquinolin-6(5H)-ones

被引：13

作者：

Tang, Yucai ^{[1
,2
,3
]}

Li, Min ^{[1
]}

Huang, Hongxin ^{[1
]}

Wang, Feifei ^{[1
]}

Hu, Xia ^{[1
]}

Zhang, Xiangyang ^{[1
]}

机构：

[1] Hunan Univ Arts & Sci, Coll Chem & Mat Engn, Hunan Prov Cooperat Innovat Ctr Construct & Dev D, Changde 415000, Peoples R China

[2] Hunan Prov Key Lab Water Treatment Funct Mat, Changde 415000, Peoples R China

[3] Hunan Prov Engn Res Ctr Electroplating Wastewater, Changde 415000, Peoples R China

来源：

SYNLETT | 2021年 / 32卷 / 12期

关键词：

iron catalysis; carbazates; hydrazinecarboxylates; alkoxycarbonylation; benzimidazoisoquinolinones; alkenes; CARBONYLATION REACTIONS; BENZIMIDAZOLES; ALCOHOLS;

D O I：

10.1055/a-1469-5742

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A FeCl2 center dot 4H(2)O-catalyzed oxidative alkoxycarbonylation of activated alkenes with carbazates toward alkoxycarbonylated benzimidazo[2,1-a]isoquinolin-6(5H)-ones has been established. The reaction proceeded smoothly to furnish a series of structurally diverse benzimidazo[2,1-a]isoquinolin-6(5H)-one frameworks in moderate to good yield.

引用

页码：1219 / 1222

页数：4

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