Iron-Catalyzed Oxidative Radical Alkoxycarbonylation of Activated Alkenes with Carbazates toward Alkoxycarbonylated Benzimidazo[2,1-a]isoquinolin-6(5H)-ones

被引：13
|
作者：
Tang, Yucai [1 ,2 ,3 ]
Li, Min [1 ]
Huang, Hongxin [1 ]
Wang, Feifei [1 ]
Hu, Xia [1 ]
Zhang, Xiangyang [1 ]
机构：
[1] Hunan Univ Arts & Sci, Coll Chem & Mat Engn, Hunan Prov Cooperat Innovat Ctr Construct & Dev D, Changde 415000, Peoples R China
[2] Hunan Prov Key Lab Water Treatment Funct Mat, Changde 415000, Peoples R China
[3] Hunan Prov Engn Res Ctr Electroplating Wastewater, Changde 415000, Peoples R China
来源：
SYNLETT | 2021年 / 32卷 / 12期
关键词：
iron catalysis; carbazates; hydrazinecarboxylates; alkoxycarbonylation; benzimidazoisoquinolinones; alkenes; CARBONYLATION REACTIONS; BENZIMIDAZOLES; ALCOHOLS;
D O I：
10.1055/a-1469-5742
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A FeCl2 center dot 4H(2)O-catalyzed oxidative alkoxycarbonylation of activated alkenes with carbazates toward alkoxycarbonylated benzimidazo[2,1-a]isoquinolin-6(5H)-ones has been established. The reaction proceeded smoothly to furnish a series of structurally diverse benzimidazo[2,1-a]isoquinolin-6(5H)-one frameworks in moderate to good yield.
引用
收藏
页码：1219 / 1222
页数：4
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