Iron-Catalyzed Oxidative Radical Alkoxycarbonylation of Activated Alkenes with Carbazates toward Alkoxycarbonylated Benzimidazo[2,1-a]isoquinolin-6(5H)-ones

被引：13

作者：

Tang, Yucai ^{[1
,2
,3
]}

Li, Min ^{[1
]}

Huang, Hongxin ^{[1
]}

Wang, Feifei ^{[1
]}

Hu, Xia ^{[1
]}

Zhang, Xiangyang ^{[1
]}

机构：

[1] Hunan Univ Arts & Sci, Coll Chem & Mat Engn, Hunan Prov Cooperat Innovat Ctr Construct & Dev D, Changde 415000, Peoples R China

[2] Hunan Prov Key Lab Water Treatment Funct Mat, Changde 415000, Peoples R China

[3] Hunan Prov Engn Res Ctr Electroplating Wastewater, Changde 415000, Peoples R China

来源：

SYNLETT | 2021年 / 32卷 / 12期

关键词：

iron catalysis; carbazates; hydrazinecarboxylates; alkoxycarbonylation; benzimidazoisoquinolinones; alkenes; CARBONYLATION REACTIONS; BENZIMIDAZOLES; ALCOHOLS;

D O I：

10.1055/a-1469-5742

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A FeCl2 center dot 4H(2)O-catalyzed oxidative alkoxycarbonylation of activated alkenes with carbazates toward alkoxycarbonylated benzimidazo[2,1-a]isoquinolin-6(5H)-ones has been established. The reaction proceeded smoothly to furnish a series of structurally diverse benzimidazo[2,1-a]isoquinolin-6(5H)-one frameworks in moderate to good yield.

引用

页码：1219 / 1222

页数：4

共 50 条

[1] Silver-catalyzed decarboxylative radical cascade cyclization toward benzimidazo[2,1-a]isoquinolin-6(5H)-ones
Sun, Kai
Li, Shi-Jun
Chen, Xiao-Lan
Liu, Yan
Huang, Xian-Qiang
Wei, Dong-Hui
Qu, Ling-Bo
Zhao, Yu-Fen
Yu, Bing
CHEMICAL COMMUNICATIONS, 2019, 55 (19) : 2861 - 2864
[2] Visible light promoting fluorescein catalyzed oxidative coupling for synthesis of benzimidazo[2,1-a]isoquinolin-6(5H)-ones
Tang, Yucai
Li, Min
Dai, Kaiming
Xiang, Xingxian
Huang, Hongxin
Jingxi Huagong/Fine Chemicals, 2022, 39 (07): : 1501 - 1506
[3] Copper-Catalyzed Oxidative Cascade Cyclization of Activated Alkenes with Azobis Compounds: Access to Cyano-Substituted Benzimidazo[2,1-a]isoquinolin-6(5H)-ones
Tang, Yucai
Huang, Hongxin
Li, Min
Wang, Feifei
Hu, Xia
Zhang, Xiangyang
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2021, 57 (12) : 2010 - 2017
[4] Copper-Catalyzed Oxidative Cascade Cyclization of Activated Alkenes with Azobis Compounds: Access to Cyano-Substituted Benzimidazo[2,1-a]isoquinolin-6(5H)-ones
Yucai Tang
Hongxin Huang
Min Li
Feifei Wang
Xia Hu
Xiangyang Zhang
Russian Journal of Organic Chemistry, 2021, 57 : 2010 - 2017
[5] Metal-Free Visible-Light Promoted Radical Cyclization to Access Perfluoroalkyl-Substituted Benzimidazo[2,1-a]isoquinolin-6(5H)-ones and Indolo[2,1-a]isoquinolin-6(5H)-ones
Zeng, Fan-Lin
Sun, Kai
Chen, Xiao-Lan
Yuan, Xiao-Ya
He, Shuai-Qi
Liu, Yan
Peng, Yu-Yu
Qu, Ling-Bo
Lv, Qi-Yan
Yu, Bing
ADVANCED SYNTHESIS & CATALYSIS, 2019, 361 (22) : 5176 - 5181
[6] Visible light photoredox-catalyzed arylative cyclization to access benzimidazo[2,1-a]isoquinolin-6(5H)-ones
Meher, Prahallad
Samanta, Raj Kumar
Manna, Sourav
Murarka, Sandip
CHEMICAL COMMUNICATIONS, 2023, 59 (40) : 6092 - 6095
[7] Synthesis of sulfonylated benzimidazo[2,1-a]isoquinolin-6(5H)-ones via I2O5-induced radical relay addition/cyclization of activated alkenes with sulfonylhydrazides
Tang, Yucai
Yang, Meng
Wang, Feifei
Hu, Xia
Wang, Gang
TETRAHEDRON LETTERS, 2021, 67
[8] The construction of benzimidazo[2,1-a]isoquinolin-6(5H)-ones from N-methacryloyl-2-phenylbenzoimidazoles through radical strategies
Kang, Qing-Qing
Zhang, Wei-Kang
Ge, Guo-Ping
Zheng, Hongxing
Wei, Wen-Ting
ORGANIC & BIOMOLECULAR CHEMISTRY, 2021, 19 (41) : 8874 - 8885
[9] The synthesis of anticancer sulfonated indolo[2,1-a]isoquinoline and benzimidazo[2,1-a]isoquinolin-6(5H)-ones derivatives via a free radical cascade pathway
Pan, You-lu
Gong, Xiao-meng
Hao, Rong-rong
Zeng, Shen-xin
Shen, Zheng-rong
Huang, Wen-hai
RSC ADVANCES, 2022, 12 (16) : 9763 - 9772
[10] Metal-Free Photosynthesis of Alkylated Benzimidazo[2,1-a]isoquinoline-6(5H)-ones and Indolo[2,1-a]isoquinolin-6(5H)-ones in PEG-200
Li, Hao-Cong
Sun, Kai
Li, Xiang
Wang, Si-Yang
Chen, Xiao-Lan
He, Shuai-Qi
Qu, Ling-Bo
Yu, Bing
JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (13): : 9055 - 9066

← 1 2 3 4 5 →