Enantiodivergent total synthesis of trioxilins B3 using Sharpless asymmetric olefin dihydroxylation

被引：4

作者：

Lapitskaya, MA ^{[1
]}

Vasiljeva, LL ^{[1
]}

Demin, PM ^{[1
]}

Pivnitsky, KK ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2004年 / 14卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1070/MC2004v014n06ABEH002003

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The unknown 11, 12-threo-stereoisomers of B-type trioxilins, (10R, 11R, 12S)-TrXB3, its (10S)-epimer and their enantiomers were synthesized (as methyl esters) from a common racemic precursor, viz., methyl rac-10-hydroxyeicos-11 (E)-ene-5,8,14-triynoate, by Sharpless enantiodirected dihydroxylation of the double bond as the key step.

引用

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页码：287 / 290

页数：4

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