Uranyl complexes with 1,2-cycloheptanedione dioxime

被引：2

作者：

Beirakhov, A. G. ^{[1
]}

Orlova, I. M. ^{[1
]}

Il'in, E. G. ^{[1
]}

Churakov, A. V. ^{[1
]}

Mikhailov, Yu. N. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 55卷 / 10期

关键词：

Uranyl; Coordination Mode; Binuclear Complex; DMSO Molecule; Uranyl Complex;

D O I：

10.1134/S0036023610100098

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Uranyl compounds with 1,2-cycloheptanedione dioxime (heptoxime) have been studied. Partial isomerization of the ligand takes place upon the formation of aqua complexes. The coordination modes of heptoxime in uranyl complexes were established by X-ray crystallography on [(UO(2))(2)(C(7)H(10)N(2)O(2))(2){(CH(3))(2)SO}(3)] single crystals: cis-(E,E)tetradentate chelating bridging and cis-(E,Z)pentadentate chelating bridging.

引用

页码：1546 / 1551

页数：6

共 50 条

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