Copper(II)-mediated oxidation of 1,2-dioxime to furoxan

被引：22
|
作者：
Das, Oindrila [1 ]
Paria, Sayantan [1 ]
Paine, Tapan Kanti [1 ]
机构：
[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, 2A&2B Raja SC Mullick Rd, Kolkata 700032, India
来源：
TETRAHEDRON LETTERS | 2008年 / 49卷 / 41期
关键词：
copper; oxidation; dioxime; furoxan;
D O I：
10.1016/j.tetlet.2008.07.148
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
1,2-Dioximes undergo oxidative transformation mediated by copper(II) ions in acetonitrile to form the corresponding furoxans in high yields. A series of 1,2-dioximes including aliphatic, aromatic, and heterocyclic dioximes were oxidized using these mild conditions. (C) 2008 Elsevier Ltd. All rights reserved.
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页码：5924 / 5927
页数：4
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