High-frequency EPR of octahedral Mn(II) compounds with large zero-field splittings

被引：24
|
作者：
Goodgame, DML
El Mkami, H
Smith, GM
Zhao, JP
McInnes, EJL
机构：
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England
[2] Univ St Andrews, Sch Phys & Astron, St Andrews KY16 9AJ, Fife, Scotland
[3] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England
来源：
DALTON TRANSACTIONS | 2003年 / 01期
关键词：
SPECTROSCOPY; COMPLEXES; RESONANCE; ION;
D O I：
10.1039/b210407p
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The use of HF-EPR to determine large zero-field splittings in distorted octahedral, high-spin d(5) ions is demonstrated with two Mn(II) coordination polymers, giving detail on both electronic and geometric structure.
引用
收藏
页码：34 / 35
页数：2
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