High-frequency EPR: An occasion for revisiting ligand field theory

被引：0
|
作者：
D. Gatteschi
L. Sorace
R. Sessoli
A. L. Barra
机构：
[1] University of Florence and Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali,Department of Chemistry
[2] Unità di Ricerca Firenze,Grenoble High Magnetic Field Laboratory
[3] Centre National de la Recherche Scientifique and Max-Planck-Institut für Festkörperphysik,Dipartimento di Chimica
[4] Università degli Studi di Firenze,undefined
来源：
Applied Magnetic Resonance | 2001年 / 21卷
关键词：
Electron Paramagnetic Reso; Ligand Field; Integer Spin; Electron Paramagnetic Reso; Transverse Anisotropy;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The use of high-field electron paramagnetic resonance (EPR) made possible for the first time to obtain detailed information on the anisotropy of integer-spin systems, which are usually silent at conventional EPR frequencies. The data obtained so far by different research groups on non-Kramers ions are reviewed within the framework of ligand field theory at different levels of approximations. Special attention is paid to the use of the angular overlap model, which resulted to be very powerful both in terms of qualitative and quantitative explanation of the experimental results.
引用
收藏
页码：299 / 310
页数：11
相关论文
共 50 条
  • [1] High-frequency EPR: an occasion for revisiting ligand field theory
    Gatteschi, D
    Sorace, L
    Sessoli, R
    Barra, AL
    [J]. APPLIED MAGNETIC RESONANCE, 2001, 21 (3-4) : 299 - 310
  • [2] High-field and high-frequency EPR
    G. R. Eaton
    S. S. Eaton
    [J]. Applied Magnetic Resonance, 1999, 16 : 161 - 166
  • [3] High-field and high-frequency EPR
    Eaton, GR
    Eaton, SS
    [J]. APPLIED MAGNETIC RESONANCE, 1999, 16 (02) : 161 - 166
  • [4] Pulsed-high Field/High-frequency EPR spectroscopy
    Fuhs, M
    Möbius, K
    [J]. HIGH MAGNETIC FIELDS: APPLICATIONS IN CONDENSED MATTER PHYSICS AND SPECTROSCOPY, 2001, 595 : 476 - 493
  • [5] High-Frequency and -Field EPR Spectroscopy of Iron(IV)
    Krzystek, J.
    Ozarowski, A.
    Telser, J.
    England, J.
    Rohde, G. T.
    Que, L.
    Nieto, I.
    Bontchev, R. P.
    Smith, J. M.
    Collins, T. J.
    [J]. JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 2014, 19 : S144 - S144
  • [6] High-frequency/high-field EPR spectroscopy of metalloproteins and models
    Hagen, WR
    [J]. JOURNAL OF INORGANIC BIOCHEMISTRY, 1999, 74 (1-4) : 28 - 28
  • [7] High-Frequency EPR Instrumentation
    Reijerse, Edward J.
    [J]. APPLIED MAGNETIC RESONANCE, 2010, 37 (1-4) : 795 - 818
  • [8] High-Frequency EPR Instrumentation
    Edward J. Reijerse
    [J]. Applied Magnetic Resonance, 2010, 37 : 795 - 818
  • [9] Theory of EPR lineshape in samples concentrated in paramagnetic spins: Effect of enhanced internal magnetic field on high-field high-frequency (HFHF) EPR lineshape
    Misra, Sushil K.
    Diehl, Stefan
    [J]. JOURNAL OF MAGNETIC RESONANCE, 2012, 219 : 53 - 60
  • [10] The Umbella high-frequency EPR facility
    P. J. M. van Bentum
    E. van der Horst
    M. E. J. Boonman
    A. Priem
    W. R. Hagen
    E. J. Reijerse
    M. Gross
    P. Goy
    M. Martinelli
    A. Colligiani
    [J]. Applied Magnetic Resonance, 2000, 19 : 479 - 484
12345