Lithium insertion/extraction reaction on crystalline MoO3

被引：145
|
作者：
Tsumura, T [1 ]
Inagaki, M [1 ]
机构：
[1] Hokkaido Univ, Fac Engn, Kita Ku, Sapporo, Hokkaido 060, Japan
来源：
SOLID STATE IONICS | 1997年 / 104卷 / 3-4期
关键词：
molybdenum trioxide; XRD measurement; van der Waals gap; co-insertion of solvent;
D O I：
10.1016/S0167-2738(97)00418-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Electrochemical lithium insertion/extraction reaction on three MoO3 samples with different crystallinity, which were heat-treated at 300, 600, and 750 degrees C, was studied, and the structural change of the host MoO3 during the lithium insertion/extraction process was followed by XRD measurements on the oriented cathode plates in a reflection and transmission arrangement. The possibility of the insertion of solvated lithium ions into the van der Waals gap and of the accommodation of some of the lithium ions into the sites in the Mo-O octahedron layers were expected. A scheme of lithium insertion into crystalline MoO3 was discussed.
引用
收藏
页码：183 / 189
页数：7
相关论文
共 50 条
  • [41] Interactions in the LiPO3 — MoO3, NaPO3 — MoO3, and KPO3 — MoO3 systems
    V. V. Lisnyak
    M. S. Slobodyanik
    V. S. Sudavtsova
    [J]. Powder Metallurgy and Metal Ceramics, 2000, 39 : 139 - 145
  • [42] Large-scale organizations of MoO3 nanoplatelets with single-crystalline MoO3(4,4′-bipyridyl)0.5
    Wei, XM
    Zeng, HC
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (12): : 2619 - 2622
  • [43] Influence of Lithium Insertion on the Electronic Transport in Electroactive MoO3 Nanobelts and Classical Powders: Morphological and Particle Size Effects
    Berthumeyrie, S.
    Badot, J. -C.
    Pereira-Ramos, J-P.
    Dubrunfaut, O.
    Bach, S.
    Vermaut, Ph.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (46): : 19803 - 19814
  • [44] A flexible ultraviolet photodetector based on single crystalline MoO3 nanosheets
    Zheng, Qinghong
    Huang, Jin
    Cao, Shilin
    Gao, Haili
    [J]. JOURNAL OF MATERIALS CHEMISTRY C, 2015, 3 (28) : 7469 - 7475
  • [45] Extrinsic Defects in Crystalline MoO3: Solubility and Effect on the Electronic Structure
    Lambert, D. S.
    Lennon, A.
    Burr, P. A.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2018, 122 (48): : 27241 - 27249
  • [46] Hydrothermal route to single crystalline α-MoO3 nanobelts and hierarchical structures
    Wang, ST
    Zhang, YG
    Ma, XC
    Wang, WZ
    Li, XB
    Zhang, ZD
    Qian, YT
    [J]. SOLID STATE COMMUNICATIONS, 2005, 136 (05) : 283 - 287
  • [47] Fabrication of single-crystalline MoO3 nanobelts by using carbons
    Ogihara, H
    Takenaka, S
    Yamanaka, I
    Tanabe, E
    Genseki, A
    Otsuka, K
    [J]. CHEMISTRY LETTERS, 2005, 34 (10) : 1428 - 1429
  • [48] Electron beam-induced structural transformations of MoO3 and MoO3-x crystalline nanostructures
    Diaz-Droguett, D. E.
    Zuniga, A.
    Solorzano, G.
    Fuenzalida, V. M.
    [J]. JOURNAL OF NANOPARTICLE RESEARCH, 2012, 14 (01)
  • [49] ANOMALIES OF MOO3
    SCHRODER, FA
    FELSER, H
    [J]. JOURNAL OF THE LESS-COMMON METALS, 1969, 18 (04): : 434 - &
  • [50] MoO3 − δ nanorods
    V. L. Volkov
    G. S. Zakharova
    M. V. Kuznetsov
    [J]. Russian Journal of Inorganic Chemistry, 2008, 53 : 1686 - 1690
12345