Lithium insertion/extraction reaction on crystalline MoO3

被引：145

作者：

Tsumura, T ^{[1
]}

Inagaki, M ^{[1
]}

机构：

[1] Hokkaido Univ, Fac Engn, Kita Ku, Sapporo, Hokkaido 060, Japan

来源：

SOLID STATE IONICS | 1997年 / 104卷 / 3-4期

关键词：

molybdenum trioxide; XRD measurement; van der Waals gap; co-insertion of solvent;

D O I：

10.1016/S0167-2738(97)00418-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electrochemical lithium insertion/extraction reaction on three MoO3 samples with different crystallinity, which were heat-treated at 300, 600, and 750 degrees C, was studied, and the structural change of the host MoO3 during the lithium insertion/extraction process was followed by XRD measurements on the oriented cathode plates in a reflection and transmission arrangement. The possibility of the insertion of solvated lithium ions into the van der Waals gap and of the accommodation of some of the lithium ions into the sites in the Mo-O octahedron layers were expected. A scheme of lithium insertion into crystalline MoO3 was discussed.

引用

页码：183 / 189

页数：7

共 50 条

[21] Effects of amorphous and crystalline MoO3 coatings on the Li-ion insertion behavior of a TiO2 nanotube anode for lithium ion batteries
Guan, Dongsheng
Li, Jianyang
Gao, Xianfeng
Yuan, Chris
[J]. RSC ADVANCES, 2014, 4 (08): : 4055 - 4062
[22] Insertion of poly(p-phenylenevinylene) in layered MoO3
[J]. 1600, (114):
[23] INSERTION OF POLY(PARA-PHENYLENEVINYLENE) IN LAYERED MOO3
NAZAR, LF
ZHANG, Z
ZINKWEG, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (15) : 6239 - 6240
[24] Lithium Intercalation Studies on MoO3 Single Crystals
Hatzikraniotis, E.
Samaras, I.
Paraskevopoulos, K. M.
Julien, C.
[J]. IONICS, 1996, 2 (01) : 24 - 28
[25] Single crystalline flowerlike α-MoO3 nanorods and their application as anode material for lithium-ion batteries
Nadimicherla, Reddeppa
Zha, Ruhua
Wei, Lu
Guo, Xin
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 687 : 79 - 86
[26] High capacity MoO3/rGO nanocomposite anode for lithium ion batteries: an intuition into the conversion mechanism of MoO3
Patil, Shivaraj B.
Udayabhanu
Kishore, Brij
Nagaraju, G.
Dupont, Jairton
[J]. NEW JOURNAL OF CHEMISTRY, 2018, 42 (23) : 18569 - 18577
[27] A two-electron mechanism of lithium insertion into layered α-MoO3: a DFT and DFT+U study
Baldoni, Matteo
Craco, Luis
Seifert, Gotthard
Leoni, Stefano
[J]. JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (05) : 1778 - 1784
[28] Structural evolution in crystalline MoO3 nanoparticles with tunable size
Santos, Elias de Barros
Sigoli, Fernando Aparecido
Mazali, Italo Odone
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 2012, 190 : 80 - 84
[29] Reduction of a two-dimensional crystalline MoO3 monolayer
Surnev, Svetlozar
Goniakowski, Jacek
Mohammadi, Malihe
Noguera, Claudine
Netzer, Falko P.
[J]. SURFACE SCIENCE, 2024, 750
[30] Amorphous-crystalline transition studied in hydrated MoO3
Carnacho-Lopez, M. A.
Haro-Poniatowski, E.
Lartundo-Rojas, L.
Livage, J.
Julien, C. M.
[J]. MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2006, 135 (02): : 88 - 94

← 1 2 3 4 5 →