Lithium insertion/extraction reaction on crystalline MoO3

被引：145
|
作者：
Tsumura, T [1 ]
Inagaki, M [1 ]
机构：
[1] Hokkaido Univ, Fac Engn, Kita Ku, Sapporo, Hokkaido 060, Japan
来源：
SOLID STATE IONICS | 1997年 / 104卷 / 3-4期
关键词：
molybdenum trioxide; XRD measurement; van der Waals gap; co-insertion of solvent;
D O I：
10.1016/S0167-2738(97)00418-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Electrochemical lithium insertion/extraction reaction on three MoO3 samples with different crystallinity, which were heat-treated at 300, 600, and 750 degrees C, was studied, and the structural change of the host MoO3 during the lithium insertion/extraction process was followed by XRD measurements on the oriented cathode plates in a reflection and transmission arrangement. The possibility of the insertion of solvated lithium ions into the van der Waals gap and of the accommodation of some of the lithium ions into the sites in the Mo-O octahedron layers were expected. A scheme of lithium insertion into crystalline MoO3 was discussed.
引用
收藏
页码：183 / 189
页数：7
相关论文
共 50 条
  • [1] Electrochemical lithium insertion/extraction in partially reduced α-MoO3
    Hashem, AM
    Abbas, H
    Abdel-Ghany, AE
    [J]. ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2004, 218 (11): : 1259 - 1272
  • [2] ELECTROCHEMICAL STUDIES OF LITHIUM INSERTION IN MOO3 FILMS
    JULIEN, C
    HUSSAIN, OM
    ELFARH, L
    BALKANSKI, M
    [J]. SOLID STATE IONICS, 1992, 53 (pt 1) : 400 - 404
  • [3] Two-phase reaction mechanism during chemical lithium insertion into α-MoO3
    A. M. Hashem
    M. H. Askar
    M. Winter
    J. H. Albering
    J. O. Besenhard
    [J]. Ionics, 2007, 13 : 3 - 8
  • [4] Two-phase reaction mechanism during chemical lithium insertion into α-MoO3
    Hashem, A. M.
    Askar, M. H.
    Winter, M.
    Albering, J. H.
    Besenhard, J. O.
    [J]. IONICS, 2007, 13 (01) : 3 - 8
  • [5] Electrochemical lithium insertion in β-MoO3: novel LixMoO3 bronzes
    I. Juárez Ramírez
    A. Martínez-de la Cruz
    [J]. Journal of Solid State Electrochemistry, 2003, 7 : 259 - 263
  • [6] Electrochemical lithium insertion in β-MoO3:: novel LixMoO3 bronzes
    Ramírez, IJ
    Martínez-de la Cruz, A
    [J]. JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2003, 7 (05) : 259 - 263
  • [7] LITHIUM INTERCALATION IN MOO3 - A COMPARISON BETWEEN CRYSTALLINE AND DISORDERED PHASES
    JULIEN, C
    KHELFA, A
    GUESDON, JP
    GORENSTEIN, A
    [J]. APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1994, 59 (02): : 173 - 178
  • [8] SOME INSERTION COMPOUNDS OF MOO3
    DICKENS, PG
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1978, 176 (SEP): : 131 - 131
  • [9] Lithium insertion in poly(ethylene oxide)/MoO3 xerogel nanocomposite films
    Hu Yong-sheng
    Chen Wen
    Xu Qing
    Yuan Run-zhang
    [J]. Journal of Wuhan University of Technology-Mater. Sci. Ed, 2002, 17 (4): : 29 - 31
  • [10] Lithium Insertion in Poly(ethylene oxide)/MoO3 Xerogel Nanocomposite Films
    胡勇胜
    [J]. Journal of Wuhan University of Technology(Materials Science), 2002, (04) : 29 - 31
12345