Palladium-catalyzed decarbonylative and decarboxylative cross-coupling of acyl chlorides with potassium perfluorobenzoates affording unsymmetrical biaryls

被引：9
|
作者：
Fu, Liyan [1 ]
You, Jingwen [1 ]
Nishihara, Yasushi [2 ]
机构：
[1] Okayama Univ, Grad Sch Nat Sci & Technol, Kita Ku, 3-1-1 Tsushimanaka, Okayama 7008530, Japan
[2] Okayama Univ, Res Inst Interdisciplinary Sci, Kita Ku, 3-1-1 Tsushimanaka, Okayama 7008530, Japan
来源：
CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 30期
关键词：
Chlorine compounds;
D O I：
10.1039/d1cc00202c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This paper describes the synthesis of unsymmetrical biaryls by the palladium-catalyzed cross-coupling reaction of acyl chlorides with potassium perfluorobenzoates. This transformation is unique in that it involves simultaneous decarbonylation and decarboxylation under redox-neutral conditions. Compared to conventional cross-coupling protocols for the synthesis of unsymmetrical biaryls, the two reactants in this synthetic strategy can be readily prepared from abundant and inexpensive aromatic carboxylic acids.
引用
收藏
页码：3696 / 3699
页数：4
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