Palladium-catalyzed decarbonylative and decarboxylative cross-coupling of acyl chlorides with potassium perfluorobenzoates affording unsymmetrical biaryls

被引：9

作者：

Fu, Liyan ^{[1
]}

You, Jingwen ^{[1
]}

Nishihara, Yasushi ^{[2
]}

机构：

[1] Okayama Univ, Grad Sch Nat Sci & Technol, Kita Ku, 3-1-1 Tsushimanaka, Okayama 7008530, Japan

[2] Okayama Univ, Res Inst Interdisciplinary Sci, Kita Ku, 3-1-1 Tsushimanaka, Okayama 7008530, Japan

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 30期

关键词：

Chlorine compounds;

D O I：

10.1039/d1cc00202c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper describes the synthesis of unsymmetrical biaryls by the palladium-catalyzed cross-coupling reaction of acyl chlorides with potassium perfluorobenzoates. This transformation is unique in that it involves simultaneous decarbonylation and decarboxylation under redox-neutral conditions. Compared to conventional cross-coupling protocols for the synthesis of unsymmetrical biaryls, the two reactants in this synthetic strategy can be readily prepared from abundant and inexpensive aromatic carboxylic acids.

引用

页码：3696 / 3699

页数：4

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