A novel 3D (4,8)-connected metal-organic framework of scu topology with two types of 1D channel constructed by methylenediisophthalic acid (H4MDIP)

被引：12

作者：

Cheng, Xian ^{[1
]}

Duan, Xian-ying ^{[1
]}

Liu, Tao ^{[1
]}

Wang, Fang-ming ^{[1
]}

Lu, Chang-sheng ^{[1
]}

Meng, Qing-jin ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Nanjing Natl Lab Microstruct,Coordinat Chem Inst, Nanjing 210093, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 07期

基金：

中国国家自然科学基金;

关键词：

Methylenediisophthalic acid (H4DMIP); Pentanuclear cluster; Topology Porous framework; Luminescence; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; POLYCATENATION; NETWORKS; LIGANDS; DESIGN;

D O I：

10.1016/j.inoche.2010.03.048

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel coordination polymer 1 {[Zn-5(MDIP)(2)(H2O)(6)(mu(3)-OH)(2)]center dot 2H(2)O} has been synthesized using methylenediisophthalic acid (H4MDIP) under hydrothermal conditions. Single-crystal X-ray diffraction analysis indicates that 1 shows a 3D porous framework with two types of 1D channel. The structure is further simplified by topology analysis which indicates a (4, 8)-connected net with a Schlafli symbol of (4(4).6(2))2 (4(16).6(12)) topology. Moreover, compound 1 displays a strong blue photoluminescent property. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：818 / 821

页数：4

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