A novel 3D (4,8)-connected metal-organic framework of scu topology with two types of 1D channel constructed by methylenediisophthalic acid (H4MDIP)

被引：12
|
作者：
Cheng, Xian [1 ]
Duan, Xian-ying [1 ]
Liu, Tao [1 ]
Wang, Fang-ming [1 ]
Lu, Chang-sheng [1 ]
Meng, Qing-jin [1 ]
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Nanjing Natl Lab Microstruct,Coordinat Chem Inst, Nanjing 210093, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 07期
基金：
中国国家自然科学基金;
关键词：
Methylenediisophthalic acid (H4DMIP); Pentanuclear cluster; Topology Porous framework; Luminescence; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; POLYCATENATION; NETWORKS; LIGANDS; DESIGN;
D O I：
10.1016/j.inoche.2010.03.048
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel coordination polymer 1 {[Zn-5(MDIP)(2)(H2O)(6)(mu(3)-OH)(2)]center dot 2H(2)O} has been synthesized using methylenediisophthalic acid (H4MDIP) under hydrothermal conditions. Single-crystal X-ray diffraction analysis indicates that 1 shows a 3D porous framework with two types of 1D channel. The structure is further simplified by topology analysis which indicates a (4, 8)-connected net with a Schlafli symbol of (4(4).6(2))2 (4(16).6(12)) topology. Moreover, compound 1 displays a strong blue photoluminescent property. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：818 / 821
页数：4
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