Synthesis, Spectroscopic Characterization, and XAFS Studies of Cu(II) Complexes with Bidentate Schiff Bases Derived from 2-Hydroxy-1-Naphthaldehyde

被引：1
|
作者：
Shukla, Kritika [1 ,2 ]
Sharma, Pradeep [2 ]
Mishra, Ashutosh [1 ]
机构：
[1] Devi Ahilya Vishwavidyalaya, Sch Phys, Indore, India
[2] Govt Holkar Model Autonomous Sci Coll, Indore, India
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2021年 / 95卷 / SUPPL 1期
关键词：
Schiff base; complexes; transition metal; ligand; XRD; XAFS; TRANSITION-METAL-COMPLEXES; CRYSTAL-STRUCTURE DETERMINATION; CATALYTIC-ACTIVITY; COORDINATION CHEMISTRY; OXIDATIVE BROMINATION; EPOXIDATION; LIGANDS; COBALT; SEM; XRD;
D O I：
10.1134/S0036024421140211
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The new complexes of compositions [CuL1] and [CuL2] were prepared by treating with [1-(((4-nitrophenyl)imino)methyl)naphthalene-2-ol] (L1) and [1-(((4-chlorophenyl)imino)methyl)naphthalene-2-ol] (L2) ligands with Cu(OAc)(2)center dot H2O, respectively. Both Schiff base ligand act as bidentate ligands. The complexes were investigated by single crystal X-ray diffraction (XRD), X-ray absorption fine structure (XAFS), Fourier transform infrared spectroscopy (FTIR), and field emission scanning electron microscopy (FE-SEM). The X-ray diffraction studies suggest a monoclinic crystal system for the complexes.
引用
收藏
页码：S128 / S139
页数：12
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