Synthesis, Spectroscopic Characterization, and XAFS Studies of Cu(II) Complexes with Bidentate Schiff Bases Derived from 2-Hydroxy-1-Naphthaldehyde

被引：1

作者：

Shukla, Kritika ^{[1
,2
]}

Sharma, Pradeep ^{[2
]}

Mishra, Ashutosh ^{[1
]}

机构：

[1] Devi Ahilya Vishwavidyalaya, Sch Phys, Indore, India

[2] Govt Holkar Model Autonomous Sci Coll, Indore, India

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2021年 / 95卷 / SUPPL 1期

关键词：

Schiff base; complexes; transition metal; ligand; XRD; XAFS; TRANSITION-METAL-COMPLEXES; CRYSTAL-STRUCTURE DETERMINATION; CATALYTIC-ACTIVITY; COORDINATION CHEMISTRY; OXIDATIVE BROMINATION; EPOXIDATION; LIGANDS; COBALT; SEM; XRD;

D O I：

10.1134/S0036024421140211

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The new complexes of compositions [CuL1] and [CuL2] were prepared by treating with [1-(((4-nitrophenyl)imino)methyl)naphthalene-2-ol] (L1) and [1-(((4-chlorophenyl)imino)methyl)naphthalene-2-ol] (L2) ligands with Cu(OAc)(2)center dot H2O, respectively. Both Schiff base ligand act as bidentate ligands. The complexes were investigated by single crystal X-ray diffraction (XRD), X-ray absorption fine structure (XAFS), Fourier transform infrared spectroscopy (FTIR), and field emission scanning electron microscopy (FE-SEM). The X-ray diffraction studies suggest a monoclinic crystal system for the complexes.

引用

页码：S128 / S139

页数：12

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