Quincoridine-based aminophosphite ligands and their Rh(I) and Pd(II) complexes

被引:14
|
作者
Polosukhin, AI
Gavrilov, KN
Bondarev, OG
Korostylev, AV
Petrovskii, PV
Davankov, VA
机构
[1] Ryazan State Pedag Univ, Dept Chem, Ryazan 390000, Russia
[2] Russian Acad Sci, Inst Organoelement Cpds, Moscow 117813, Russia
基金
俄罗斯基础研究基金会;
关键词
aminophosphites; P; N-ligands; chirality; quincoridine derivatives; rhodium complexes; palladium complexes;
D O I
10.1016/S0022-328X(00)00373-9
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
New chiral P,N-bidentate ligands containing a quincoridine fragment with a configuration-stable N-donating center were obtained. Coordination of the ligands to Rh(I) and Pd(II) atoms was carried out. Chlorocarbonyl rhodium and dichloride palladium complexes were found to be cis-chelates with P,N-bidentate ligands. (C) 2000 Published by Elsevier Science S.A.
引用
收藏
页码:89 / 95
页数:7
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