Azobenzene Pd(II) complexes with ligands

被引:0
|
作者
Nikolaeva, M. V. [1 ]
Puzyk, An. M. [1 ]
Puzyk, M. V. [1 ]
机构
[1] Herzen State Pedag Univ Russia, St Petersburg 191186, Russia
关键词
RAY CRYSTAL-STRUCTURE; CYCLOPALLADATED COMPLEXES; LUMINESCENT PROPERTIES; PALLADIUM COMPLEXES; ORTHO-PALLADATION; AMINO-ACIDS; CARBONYLATION; DERIVATIVES; NITROGEN; CARBON;
D O I
10.1134/S0030400X17050174
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Methods of synthesis of cyclometalated azobenzene palladium(II) complexes of [Pd(N<^>N)Azb]ClO4 and [Pd(N<^>O)Azb]ClO4 types (where Azb(-) is the deprotonated form of azobenzene; N<^>N is 2NH(3), ethylenediamine, or 2,2'-bipyridine; and (N<^>O)(-) is the deprotonated form of amino acid (glycine, alpha-alanine, beta-alanine, tyrosine, or tryptophan)) are developed. The electronic absorption and the electrochemical properties of these complexes are studied.
引用
收藏
页码:715 / 722
页数:8
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