Catalytic enantioselective addition of diethylzinc to aldehydes using aziridine based chiral ligands

被引：28
|
作者：
Bulut, Adnan
Aslan, Ayhan
Izgu, Enver Cagri
Dogan, Oezdemir [1 ]
机构：
[1] Kirikkale Univ, Dept Chem, TR-71450 Kirikkale, Turkey
[2] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey
来源：
TETRAHEDRON-ASYMMETRY | 2007年 / 18卷 / 08期
关键词：
D O I：
10.1016/j.tetasy.2007.04.013
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The readily available ferrocenyl substituted aziridinylmethanol 1 (FAM-1) was used as a chiral catalyst in the diethylzinc addition reaction to aromatic and aliphatic aldehydes to give secondary alcohols in high yields and up to 99% enantiomeric excess at room temperature. The catalyst can be recovered and used without losing its activity. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1013 / 1016
页数：4
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