THERMAL DECOMPOSITION OF WOOD FIBERS: THERMAL SIMULATION USING THE F-TEST STATISTICAL TOOL

被引:0
|
作者
Ornaghi, Heitor L., Jr. [1 ]
Ornaghi, Felipe Gustavo [2 ]
Neves, Roberta Motta [3 ]
De Oliveira, Daniel Magalhaes [4 ]
Poletto, Matheus [3 ]
机构
[1] Fed Univ Latin Amer Integrat UNILA, Foz Do Iguacu, PR, Brazil
[2] Univ Fed Rio Grande do Sul, Postgrad Program Min Met & Mat Engn PPGE3M, Av Bento Goncalves 9500, Porto Alegre, RS, Brazil
[3] Univ Caxias do Sul UCS, Campus Sede,R Francisco Getulio Vargas 1130, Petropolis, RS, Brazil
[4] Sao Paulo State Univ UNESP, Sch Engn, Fatigue & Aeronaut Mat Res Grp, Dept Mat & Technol, Guaratingueta, SP, Brazil
来源
CELLULOSE CHEMISTRY AND TECHNOLOGY | 2021年 / 55卷 / 3-4期
关键词
modelling and simulation; wood fiber; thermal decomposition; pyrolysis; model-fitting; SOLID-STATE REACTIONS; KINETIC-ANALYSIS; THERMOGRAVIMETRIC ANALYSIS; COMPENSATION BEHAVIOR; NATURAL FIBERS; DEGRADATION; PARAMETERS; COMPOSITES; PYROLYSIS; BIOMASS;
D O I
10.35812/CELLULOSECHEMTECHNOL.2021.55.23
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
Wood biomass is an alternative for fossil fuels to produce bioenergy, due to its low cost, renewability and environmental friendliness. In order to use biomass as an energy source, understanding its thermal degradation behavior is highly recommended. This work focuses on the thermal degradation of wood fibers belonging to different species (Pinus elliotti (PIE), Eucalyptus grandis (EUG) and Mezilaurus itauba (ITA)), commonly used by the Brazilian lumber industry. The prediction of their degradation kinetics and overall thermal behavior was performed based on the most common theoretical data using the F-test statistical tool. The most probable degradation mechanism was found to be autocatalytic for all the wood fibers tested, with three different degradation steps. The results obtained were in accordance with the findings recently reported in the literature using other fitting methods. It was found that cellulose is the major contributor to Arrhenius parameters, while hemicelluloses - to reaction order.
引用
收藏
页码:231 / 241
页数:11
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