Weak intermolecular interaction directed assembly of calix[4]arene derivatives

被引：1

作者：

Xiao, Zufeng ^{[1
]}

Yang, Weiping ^{[2
]}

Luo, Jia ^{[3
]}

Guo, Rong ^{[4
]}

Zeng, Rong ^{[4
]}

Ji, Lingbo ^{[2
]}

Li, Wei ^{[1
]}

Wang, Wei ^{[1
]}

机构：

[1] Hubei Engn Univ, Sch Chem & Mat Sci, Xiaogan 430000, Hubei, Peoples R China

[2] Zhengzhou Tobacco Res Inst CNTC, Key Lab Tobacco Flavor Basic Res, Zhengzhou 450001, Henan, Peoples R China

[3] Hubei Engn Univ, Coll Life Sci & Technol, Xiaogan 130000, Hubei, Peoples R China

[4] Wuhan Inst Ind Holding Technol, Wuhan 430000, Hubei, Peoples R China

来源：

CRYSTENGCOMM | 2019年 / 21卷 / 46期

关键词：

1,3-ALTERNATE; PROPERTY;

D O I：

10.1039/c9ce01286a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystals of cone-di-formyl-calix[4]arene (16), 1,3-alt-di-O-benzoyl-di-formyl-calix[4]arene (17), 1,3-alt-tetra-O-n-propyl-tetra-formyl-calix[4]arene (18), 1,3-alt-tetra-O-i-propyl-di-formyl-calix[4]arene (19), 1,3-alt-tetra-O-i-propyl-tri-formyl-calix[4]arene (20), 1,3-alt-tetra-O-i-propyl-tetra-cyano-calix[4]arene (21), and pc-A,B-di-O-i-propyl-tetra-formyl-calix[4]arene1/2CH(2)Cl(2) (221/2CH(2)Cl(2)) obtained in crystallisation solvent chloroform-hexane have been studied. These crystals form different architectures through some weak intermolecular forces, such as C-H center dot center dot center dot O, C-H center dot center dot center dot pi, O center dot center dot center dot pi and pi center dot center dot center dot pi interactions. Compounds 16-18 form classic 'head-to-head' dimer or 'head-to-tail' dimer motifs by C-H center dot center dot center dot O interactions, while compound 22 forms an 'up-down' dimer structure via C-H center dot center dot center dot pi interactions. Compounds 19-21 adopting a 1,3-alt conformation are closely packed together by weak intermolecular interactions. The results indicate that weak intermolecular interactions can determine the assembly pathways of calix[4]arene derivatives.

引用

页码：7114 / 7122

页数：9

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