Synthesis and NLO Properties of Calix[4] arene Derivatives

被引：1
|
作者：
Fang Mingfeng [1 ]
Lu Guo-Yuan [2 ]
机构：
[1] Nanjing Forestry Univ, Coll Chem Engn, Nanjing 210037, Jiangsu, Peoples R China
[2] Nanjing Univ, Dept Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
MATERIALS AND MANUFACTURING, PTS 1 AND 2 | 2011年 / 299-300卷
基金：
中国国家自然科学基金;
关键词：
Calix[4]arene; chromophore; NLO; first molecular hyperpolarizability; CHROMOPHORES;
D O I：
10.4028/www.scientific.net/AMR.299-300.452
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A novel calix[4]arene chromophore 1 was synthesized by introduction of two D-pi-A units (4-nitrophenyl)azophenyloxy groups) on the lower rim of calix[4]arene. The measurement results of hyper-Rayleigh scattering (HRS) and UV-vis spectra show that the static first molecular hyperpolarizability of the chromophore 1 is more than two times that of the corresponding mono-D-pi-A unit reference compound 4-(4-nitrophenylazo)phenol 2, without causing red-shift of absorption band.
引用
收藏
页码：452 / +
页数：2
相关论文
共 50 条
  • [1] Synthesis of calix[4]arene derivatives with NLO properties
    Bai, Z
    Zhang, CZ
    Lu, GY
    Liu, F
    CHINESE JOURNAL OF CHEMISTRY, 2006, 24 (01) : 124 - 128
  • [2] Synthesis and properties of novel amphiphilic calix-[4]-arene derivatives
    Shahgaldian, P
    Coleman, AW
    Kalchenko, VI
    TETRAHEDRON LETTERS, 2001, 42 (04) : 577 - 579
  • [3] Synthesis of novel light emitting calix[4]arene derivatives and their luminescent properties
    Wei, Xiao-Qiang
    Yang, Gang
    Cheng, Jian-Bo
    Lu, Zhi-Yun
    Xie, Ming-Gui
    MATERIALS CHEMISTRY AND PHYSICS, 2007, 102 (2-3) : 214 - 218
  • [4] Studies on synthesis and conformation of calix[4]arene derivatives
    Lu, GY
    Chen, ZJ
    Zhao, RZ
    Huang, XH
    Hu, HW
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1996, 17 (08): : 1244 - 1246
  • [5] Synthesis and anion binding properties of the bridged urea derivatives of calix[4]arene
    Yang, YS
    Ko, SW
    Song, IH
    Ryu, BJ
    Nam, KC
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2003, 24 (05) : 681 - 683
  • [6] Synthesis and properties of novel calix[4]arene derivatives bearing fluorogenic coumarin units
    He Wen Wang Ya Qing Feng~* Jin Qiang Xue Chan Xiao School of Chemical Engineering and Technology
    ChineseChemicalLetters, 2008, (08) : 901 - 903
  • [7] Synthesis and properties of novel calix[4]arene derivatives bearing fluorogenic coumarin units
    Wang, He Wen
    Feng, Ya Qing
    Xue, Jin Qiang
    Xiao, Chan
    CHINESE CHEMICAL LETTERS, 2008, 19 (08) : 901 - 903
  • [8] Synthesis, conformations and extraction properties of new chromogenic calix[4]arene amide derivatives
    Halouani, H
    Dumazet-Bonnamour, I
    Duchamp, C
    Bavoux, C
    Ehlinger, N
    Perrin, M
    Lamartine, R
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2002, 2002 (24) : 4202 - 4210
  • [9] Synthesis of novel light-emitting calix[4]arene derivatives and their luminescent properties
    Wei, Xiao-Qiang
    Yang, Gang
    Cheng, Jian-Bo
    Lu, Zhi-Yun
    Xie, Ming-Gui
    OPTICAL MATERIALS, 2007, 29 (08) : 936 - 940
  • [10] Studies on synthesis and property of calix[4]arene derivatives(V)
    Lu, GY
    Li, Q
    Wan, XB
    Hu, HW
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2000, 20 (01) : 112 - 115
12345