Iron-Promoted C-C Bond Formation in the Gas Phase

被引：9
|
作者：
Troiani, Anna [1 ]
Rosi, Marzio [2 ,3 ]
Garzoli, Stefania [1 ]
Salvitti, Chiara [1 ]
de Petris, Giulia [1 ]
机构：
[1] Univ Roma La Sapienza, Dipartimento Chim & Tecnol Farmaco, I-00185 Rome, Italy
[2] Univ Perugia, Dipartimento Ingn Civile & Ambientale, I-06125 Perugia, Italy
[3] ISTM CNR, I-06125 Perugia, Italy
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 48期
关键词：
carbon-carbon coupling; gas-phase chemistry; ion-molecule reactions; iron; reaction mechanisms; ION-CYCLOTRON RESONANCE; COORDINATION CHEMISTRY; ELECTRON CORRELATION; SEQUENTIAL LIGATION; RADICAL CATIONS; ACTIVATION; FERROCENE; (C-C5H5)FE+; LIGANDS; STATE;
D O I：
10.1002/anie.201506932
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An unusual iron transfer and carbon-carbon coupling take place in gas-phase ionized mixtures containing ferrocene and dichloromethane. Ferrous chloride and the protonated benzenium ion are eventually formed by a thermal and efficient reaction, through stable intermediates that undergo a remarkable reorganization. The mechanism of the concerted iron extrusion, carbon-chlorine bond activation and carbon-carbon bond formation is elucidated by electronic structure calculations that show the crucial role of iron.
引用
收藏
页码：14359 / 14362
页数：4
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