Iron-Promoted C-C Bond Formation in the Gas Phase

被引：9

作者：

Troiani, Anna ^{[1
]}

Rosi, Marzio ^{[2
,3
]}

Garzoli, Stefania ^{[1
]}

Salvitti, Chiara ^{[1
]}

de Petris, Giulia ^{[1
]}

机构：

[1] Univ Roma La Sapienza, Dipartimento Chim & Tecnol Farmaco, I-00185 Rome, Italy

[2] Univ Perugia, Dipartimento Ingn Civile & Ambientale, I-06125 Perugia, Italy

[3] ISTM CNR, I-06125 Perugia, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 48期

关键词：

carbon-carbon coupling; gas-phase chemistry; ion-molecule reactions; iron; reaction mechanisms; ION-CYCLOTRON RESONANCE; COORDINATION CHEMISTRY; ELECTRON CORRELATION; SEQUENTIAL LIGATION; RADICAL CATIONS; ACTIVATION; FERROCENE; (C-C5H5)FE+; LIGANDS; STATE;

D O I：

10.1002/anie.201506932

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An unusual iron transfer and carbon-carbon coupling take place in gas-phase ionized mixtures containing ferrocene and dichloromethane. Ferrous chloride and the protonated benzenium ion are eventually formed by a thermal and efficient reaction, through stable intermediates that undergo a remarkable reorganization. The mechanism of the concerted iron extrusion, carbon-chlorine bond activation and carbon-carbon bond formation is elucidated by electronic structure calculations that show the crucial role of iron.

引用

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页码：14359 / 14362

页数：4

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