Evidence for an adiabatic reaction pathway for trans-to-cis photoisomerization of di(α-naphthyl)ethylene

被引：16
|
作者：
Budyka, MF [1 ]
Laukhina, OD [1 ]
Razumov, VF [1 ]
机构：
[1] Russian Acad Sci, Inst Chem Phys, Chernogolovka 142432, Moscow Region, Russia
来源：
CHEMICAL PHYSICS LETTERS | 1997年 / 279卷 / 5-6期
关键词：
D O I：
10.1016/S0009-2614(97)01062-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Direct photocyclization of trans-di(alpha-naphthyl)ethylene to dihydropicene with a quantum yield of 0.03 was observed. The kinetics of the photochemical transformations and the effect of the excitation intensity on the yield of dihydropicene was studied. A novel adiabatic reaction pathway for trans-to-cis photoisomerization of di(alpha-naphthyl)ethylene was suggested. (C) 1997 Elsevier Science B.V.
引用
收藏
页码：327 / 332
页数：6
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