Evidence for an adiabatic reaction pathway for trans-to-cis photoisomerization of di(α-naphthyl)ethylene

被引：16

作者：

Budyka, MF ^{[1
]}

Laukhina, OD ^{[1
]}

Razumov, VF ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Chem Phys, Chernogolovka 142432, Moscow Region, Russia

来源：

CHEMICAL PHYSICS LETTERS | 1997年 / 279卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(97)01062-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Direct photocyclization of trans-di(alpha-naphthyl)ethylene to dihydropicene with a quantum yield of 0.03 was observed. The kinetics of the photochemical transformations and the effect of the excitation intensity on the yield of dihydropicene was studied. A novel adiabatic reaction pathway for trans-to-cis photoisomerization of di(alpha-naphthyl)ethylene was suggested. (C) 1997 Elsevier Science B.V.

引用

页码：327 / 332

页数：6

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