Dielectric transition and relaxation in an imidazolium-based organic-inorganic hybrid crystal (HIm)6[(CdCl4)(CdCl6)]

被引：14
|
作者：
Yuan, Xiao-Hui [1 ]
Shao, Xiu-Dan [1 ]
Shi, Chao [1 ]
Zhang, Wen [1 ]
机构：
[1] Southeast Univ, Ordered Matter Sci Res Ctr, Nanjing 211189, Jiangsu, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2016年 / 67卷
基金：
中国国家自然科学基金;
关键词：
Phase transition; Dielectric transition; Disorder; Imidazole; Cadmium; PHASE-TRANSITION; TWISTING MOTION; CONSTANT; FERROELECTRICITY; FRAMEWORKS; DYNAMICS; STIMULI;
D O I：
10.1016/j.inoche.2016.03.001
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Organic-inorganic hybrid compound (HIm)(6)[(CdCl4)(CdCl6)] = imidazole) shows a striking dielectric transition and relaxation between 120 and 180 K.Variable-temperature single crystal structure analysis and dielectric measurement reveal one half of the HIm cations in the crystal undergoes a transition between the static and dynamic disorders. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：35 / 39
页数：5
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