Dielectric transition and relaxation in an imidazolium-based organic-inorganic hybrid crystal (HIm)6[(CdCl4)(CdCl6)]

被引：14

作者：

Yuan, Xiao-Hui ^{[1
]}

Shao, Xiu-Dan ^{[1
]}

Shi, Chao ^{[1
]}

Zhang, Wen ^{[1
]}

机构：

[1] Southeast Univ, Ordered Matter Sci Res Ctr, Nanjing 211189, Jiangsu, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2016年 / 67卷

基金：

中国国家自然科学基金;

关键词：

Phase transition; Dielectric transition; Disorder; Imidazole; Cadmium; PHASE-TRANSITION; TWISTING MOTION; CONSTANT; FERROELECTRICITY; FRAMEWORKS; DYNAMICS; STIMULI;

D O I：

10.1016/j.inoche.2016.03.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Organic-inorganic hybrid compound (HIm)(6)[(CdCl4)(CdCl6)] = imidazole) shows a striking dielectric transition and relaxation between 120 and 180 K.Variable-temperature single crystal structure analysis and dielectric measurement reveal one half of the HIm cations in the crystal undergoes a transition between the static and dynamic disorders. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：35 / 39

页数：5

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