Synthesis, crystal structure and thermoelectric properties of the ternary skutterudite Fe2Pd2Sb12

被引：8
|
作者：
Navratil, J. [2 ,3 ]
Laufek, F. [1 ]
Plechacek, T. [2 ,3 ]
Plasil, J. [4 ]
机构：
[1] Czech Geol Survey, Prague 15200 5, Czech Republic
[2] AS CR, IMC, Joint Lab Solid State Chem, Pardubice 53210, Czech Republic
[3] Univ Pardubice, Fac Chem Technol, Pardubice 53210, Czech Republic
[4] Natl Museum, Prague 11579 1, Czech Republic
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2010年 / 493卷 / 1-2期
关键词：
Fe2Pd2Sb12; Crystal structure; X-ray powder diffraction; Transport properties; TRANSPORT-PROPERTIES; ANTIMONIDES; CEFE4SB12; FE; RH; IR; CO;
D O I：
10.1016/j.jallcom.2009.12.085
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The Fe2Pd2Sb12 compound was synthesized and structurally characterized by powder X-ray diffraction. Fe2Pd2Sb12 has the skutterudite structure, Im (3) over bar symmetry, unit cell parameter a = 9.2048(2) angstrom, Z = 8. The transport properties of the title compound were investigated. From the temperature dependencies of electrical conductivity, the Hall coefficient and the Seebeck coefficient the existence of mixed conductivity mechanism by means of electrons and holes was proposed. (C) 2010 Elsevier BM. All rights reserved.
引用
收藏
页码：50 / 54
页数：5
相关论文
共 50 条
  • [41] Synthesis and crystal structure of Fe2BP3O12
    Chen, HH
    Ge, MH
    Yang, XX
    Mi, JX
    Zhao, JT
    JOURNAL OF INORGANIC MATERIALS, 2004, 19 (02) : 429 - 432
  • [42] Preparation and thermoelectric properties of the skutterudite-related phase Ru0.5Pd0.5Sb3
    J Appl Phys, 11 (8419):
  • [43] Crystal structure and thermoelectric properties of β-MoSi2
    Yamada, Takahiro
    Yamane, Hisanori
    INTERMETALLICS, 2011, 19 (07) : 908 - 912
  • [44] Preparation and thermoelectric properties of the skutterudite-related phase Ru0.5Pd0.5Sb3
    Caillat, T
    Kulleck, J
    Borshchevsky, A
    Fleurial, JP
    JOURNAL OF APPLIED PHYSICS, 1996, 79 (11) : 8419 - 8426
  • [45] Synthesis and thermoelectric properties of KyCo4Sb12
    Pei, Y. Z.
    Chen, L. D.
    Zhang, W.
    Shi, X.
    Bai, S. Q.
    Zhao, X. Y.
    Mei, Z. G.
    Li, X. Y.
    APPLIED PHYSICS LETTERS, 2006, 89 (22)
  • [46] Synthesis, Structure, and Thermoelectric Properties of α-Zn3Sb2 and Comparison to β-Zn13Sb10
    Lo, Chun-Wan Timothy
    Ortiz, Brenden R.
    Toberer, Eric S.
    He, Allan
    Svitlyk, Volodymyr
    Chernyshov, Dmitry
    Kolodiazhnyi, Taras
    Lidin, Sven
    Mozharivskyj, Yurij
    CHEMISTRY OF MATERIALS, 2017, 29 (12) : 5249 - 5258
  • [47] Enhancement of thermoelectric properties of Ce0.9Fe3.75Ni0.25Sb12 p-type skutterudite by tellurium addition
    Fu, Liangwei
    Jiang, Qinghui
    Yang, Junyou
    Peng, Jiangying
    Xiao, Ye
    Luo, Yubo
    Zhou, Zhiwei
    Zhang, Dan
    JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (42) : 16499 - 16506
  • [48] Low-Temperature Thermoelectric Properties of Co0.9Fe0.1Sb3-Based Skutterudite Nanocomposites with FeSb2 Nanoinclusions
    Chen Zhou
    Jeffery Sakamoto
    Donald Morelli
    Journal of Electronic Materials, 2011, 40 : 547 - 550
  • [49] Synthesis and thermoelectric properties of CeyRuxIr4-xSb12 filled skutterudite compounds
    Jewell, April D.
    Paik, Jong-Ah
    Caillat, Thierry
    MATERIALS AND TECHNOLOGIES FOR DIRECT THERMAL-TO-ELECTRIC ENERGY CONVERSION, 2006, 886 : 369 - +
  • [50] Low-Temperature Thermoelectric Properties of Co0.9Fe0.1Sb3-Based Skutterudite Nanocomposites with FeSb2 Nanoinclusions
    Zhou, Chen
    Sakamoto, Jeffery
    Morelli, Donald
    JOURNAL OF ELECTRONIC MATERIALS, 2011, 40 (05) : 547 - 550
12345