Synthesis, crystal structure and thermoelectric properties of the ternary skutterudite Fe2Pd2Sb12

被引：8
|
作者：
Navratil, J. [2 ,3 ]
Laufek, F. [1 ]
Plechacek, T. [2 ,3 ]
Plasil, J. [4 ]
机构：
[1] Czech Geol Survey, Prague 15200 5, Czech Republic
[2] AS CR, IMC, Joint Lab Solid State Chem, Pardubice 53210, Czech Republic
[3] Univ Pardubice, Fac Chem Technol, Pardubice 53210, Czech Republic
[4] Natl Museum, Prague 11579 1, Czech Republic
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2010年 / 493卷 / 1-2期
关键词：
Fe2Pd2Sb12; Crystal structure; X-ray powder diffraction; Transport properties; TRANSPORT-PROPERTIES; ANTIMONIDES; CEFE4SB12; FE; RH; IR; CO;
D O I：
10.1016/j.jallcom.2009.12.085
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The Fe2Pd2Sb12 compound was synthesized and structurally characterized by powder X-ray diffraction. Fe2Pd2Sb12 has the skutterudite structure, Im (3) over bar symmetry, unit cell parameter a = 9.2048(2) angstrom, Z = 8. The transport properties of the title compound were investigated. From the temperature dependencies of electrical conductivity, the Hall coefficient and the Seebeck coefficient the existence of mixed conductivity mechanism by means of electrons and holes was proposed. (C) 2010 Elsevier BM. All rights reserved.
引用
收藏
页码：50 / 54
页数：5
相关论文
共 50 条
  • [21] Solvothermal synthesis and thermoelectric properties of skutterudite compound Fe0.25Ni0.25Co0.5Sb3
    Mi Jianli
    Zhao Xinbing
    Zhu Tiejun
    RARE METALS, 2009, 28 (03) : 237 - 240
  • [22] Solvothermal synthesis and thermoelectric properties of skutterudite compound Fe0.25Ni0.25Co0.5Sb3
    Jianli Mi
    Xinbing Zhao
    Tiejun Zhu
    Rare Metals, 2009, 28 : 237 - 240
  • [23] Effect of rapid solidification on the synthesis and thermoelectric properties of Yb-filled Co4Sb12 skutterudite
    Aversano, F.
    Branz, S.
    Bassani, E.
    Fanciulli, C.
    Ferrario, A.
    Boldrini, S.
    Baricco, M.
    Castellero, A.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 796 : 33 - 41
  • [24] Crystal structure, electronic structure, and thermoelectric properties of Ca5Al2Sb6
    Yan, Yu Li
    Wang, Yuan Xu
    JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (33) : 12497 - 12502
  • [25] The synthesis of CaZn2Sb2 and its thermoelectric properties
    Stark, D
    Snyder, GJ
    XXI INTERNATIONAL CONFERENCE ON THERMOELECTRICS, PROCEEDINGS ICT '02, 2002, : 181 - 184
  • [26] Solvothermal synthesis of nanostructured ternary skutterudite Fe0.5Ni0.5Sb3
    Mi, JL
    Zhao, XB
    Zhu, TJ
    Tu, JP
    Cao, GS
    JOURNAL OF ALLOYS AND COMPOUNDS, 2005, 399 (1-2) : 260 - 263
  • [27] Ternary MIn2S4 (M = Mn, Fe, Co, Ni) Thiospinels - Crystal Structure and Thermoelectric Properties
    Wyzga, Pawel
    Veremchuk, Igor
    Bobnar, Matej
    Hennig, Christoph
    Leithe-Jasper, Andreas
    Gumeniuk, Roman
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2020, 646 (14): : 1091 - 1098
  • [28] In y Co4Sb12 Skutterudite: Phase Equilibria and Crystal Structure
    Grytsiv, A.
    Rogl, P.
    Michor, H.
    Bauer, E.
    Giester, G.
    JOURNAL OF ELECTRONIC MATERIALS, 2013, 42 (10) : 2940 - 2952
  • [29] Synthesis and basic properties of the filled skutterudite SmFe4Sb12
    Ueda, Makoto
    Kawahito, Yusuke
    Tanaka, Kenya
    Kikuchi, Daisuke
    Aoki, Hidekazu
    Sugawara, Hitoshi
    Kuwahara, Keltaro
    Aoki, Yuji
    Sato, Hideyuki
    PHYSICA B-CONDENSED MATTER, 2008, 403 (5-9) : 881 - 883
  • [30] Synthesis process and thermoelectric properties of the layered crystal structure SnS2
    Yi Chang
    Min Ruan
    Fu Li
    Zhuanghao Zheng
    Yuexing Chen
    Zhenhua Ge
    Ping Fan
    Journal of Materials Science: Materials in Electronics, 2020, 31 : 5425 - 5433
12345