The palladium-catalyzed addition of aryl- and heteroarylboronic acids to aldehydes

被引：95

作者：

Qin, Changming ^{[1
]}

Wu, Huayue ^{[1
]}

Cheng, Jiang ^{[1
]}

Chen, Xi'an ^{[1
]}

Liu, Miaochang ^{[1
]}

Zhang, Weiwei ^{[1
]}

Su, Weike ^{[1
]}

Ding, Jinchang ^{[1
]}

机构：

[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325027, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 72卷 / 11期

关键词：

D O I：

10.1021/jo070267h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of aryl- or heteroarylboronic acids with aldehydes, in the presence of PdCl2 and P(1-Nap)(3), afforded carbinol derivatives in good to excellent yields. The efficiency of this reaction was demonstrated by the compatibility with nitro, cyano, acetamido, acetoxy, acetyl, carboxyl, trifluoromethyl, fluoro, and chloro groups and the possibility of involving aliphatic aldehyde or hindered substrates. Moreover, the rigorous exclusion of air/moisture is not required in these transformations.

引用

页码：4102 / 4107

页数：6

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