Palladium-catalyzed addition of arylboronic acids to aldehydes

被引：99
|
作者：
Yamamoto, T [1 ]
Ohta, T [1 ]
Ito, Y [1 ]
机构：
[1] Doshisha Univ, Fac Engn, Dept Mol Sci & Technol, Kyoto 6100394, Japan
来源：
ORGANIC LETTERS | 2005年 / 7卷 / 19期
关键词：
D O I：
10.1021/ol051501y
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Arylboronic acids react with aldehydes in the presence of a base and a catalytic amount of a palladium(0) complex with chloroform, affording the corresponding secondary alcohols in good yields. General palladium complexes have no catalytic activity without chloroform. Chloroform is essential for this reaction, and palladium complex that was prepared from Pd(PPh3)(4) with CHCl3 showed good catalytic acitivty as well.
引用
收藏
页码：4153 / 4155
页数：3
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