Palladium-catalyzed 1,2-addition of potassium aryl- and alkenyltrifluoroborates to aldehydes using thioether-imidazolinium carbene ligands

被引：40
|
作者：
Kuriyama, Masami [1 ]
Shimazawa, Rumiko [1 ]
Enomoto, Terumichi [1 ]
Shirai, Ryuichi [1 ]
机构：
[1] Doshisha Womens Coll Liberal Arts, Fac Pharmaceut Sci, Kyoto 6100395, Japan
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 73卷 / 17期
基金：
日本学术振兴会;
关键词：
D O I：
10.1021/jo801352h
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Palladium-catalyzed 1,2-addition of potassium aryl- and alkenyltrifluoroborates to aldehydes using thioether-imidazolinium carbene ligands proceeded readily under aqueous conditions. This process tolerated a diverse range of potassium trifluoroborate salts and aldehydes, giving a variety of carbinol derivatives with good to excellent yields.
引用
收藏
页码：6939 / 6942
页数：4
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