NEW OPTICALLY ACTIVE CN-PALLADACYCLES BASED ON 2α-HYDROXYPINAN-3-ONE AND CAMPHOR DERIVATIVES

被引：5
|
作者：
Gur'eva, Ya. A. [1 ]
Zalevskaya, O. A. [2 ]
Alekseev, I. N. [1 ]
Frolova, L. L. [1 ]
Slepukhin, P. A. [3 ]
Kuchin, A. V. [1 ]
机构：
[1] Russian Acad Sci, Ural Branch, Inst Chem, Komi Sci Ctr, Ul Pervomaiskaya 48, Syktyvkar 167982, Russia
[2] Syktyvkar State Univ, Syktyvkar 167023, Russia
[3] Russian Acad Sci, Ural Branch, I Ya Postovskii Inst Organ Synth, Ekaterinburg 620137, Russia
来源：
CHEMISTRY OF NATURAL COMPOUNDS | 2014年 / 50卷 / 04期
关键词：
chiral imines; monoterpenoids; palladium; palladacycles; stereoisomers; diastereoselectivity; X-ray crystal structure analysis;
D O I：
10.1007/s10600-014-1044-3
中图分类号：
R914 [药物化学];
学科分类号：
100701 ;
摘要：
The ligand (-)-2 alpha-hydroxypinan-3-one diphenylmethylimine was synthesized and studied. New dinuclear CN-palladacycles and their mononuclear triphenylphosphine derivatives were obtained. It was shown that ortho-palladation of terpene diphenylmethylimines produced pure stereoisomers.
引用
收藏
页码：648 / 651
页数：4
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