Chiral imines and amines based on 2-hydroxypinan-3-one

被引：0
|
作者：
Ya. A. Gur’eva
O. A. Zalevskaya
L. L. Frolova
I. N. Alekseev
A. V. Kuchin
机构：
[1] Institute of Chemistry,
[2] Komi Scientific Center,undefined
[3] Ural Branch,undefined
[4] Russian Academy of Sciences,undefined
[5] Syktyvkar State University,undefined
来源：
Chemistry of Natural Compounds | 2011年 / 46卷
关键词：
chiral imines; amines; stereoisomers; stereoselectivity;
D O I：
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中图分类号：
学科分类号：
摘要：
The new chiral derivatives of benzylamine and 2α-hydroxypinan-3-one (1R,2R,5R)-3-[(1S)-α-methylbenzylamino]-2,6,6-trimethylbicyclo[3.1.1]heptan-2-ol (2), (1S,2S,3S,5S)-3-(benzylamino)-2,6,6-trimethylbicyclo[3.1.1]heptan-2-ol (3), and (1R,2R,3R,5R)-3-[(1S)-α-methylbenzylamino]-2,6,6-trimethylbicyclo[3.1.1]heptan-2-ol (4) were synthesized and characterized. It was shown that reduction of the benzylimines by sodium triacetoxyborohydride formed stereoselectively 3β-substituted pinanamines.
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页码：920 / 923
页数：3
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