NEW OPTICALLY ACTIVE CN-PALLADACYCLES BASED ON 2α-HYDROXYPINAN-3-ONE AND CAMPHOR DERIVATIVES

被引：5

作者：

Gur'eva, Ya. A. ^{[1
]}

Zalevskaya, O. A. ^{[2
]}

Alekseev, I. N. ^{[1
]}

Frolova, L. L. ^{[1
]}

Slepukhin, P. A. ^{[3
]}

Kuchin, A. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Ural Branch, Inst Chem, Komi Sci Ctr, Ul Pervomaiskaya 48, Syktyvkar 167982, Russia

[2] Syktyvkar State Univ, Syktyvkar 167023, Russia

[3] Russian Acad Sci, Ural Branch, I Ya Postovskii Inst Organ Synth, Ekaterinburg 620137, Russia

来源：

CHEMISTRY OF NATURAL COMPOUNDS | 2014年 / 50卷 / 04期

关键词：

chiral imines; monoterpenoids; palladium; palladacycles; stereoisomers; diastereoselectivity; X-ray crystal structure analysis;

D O I：

10.1007/s10600-014-1044-3

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

The ligand (-)-2 alpha-hydroxypinan-3-one diphenylmethylimine was synthesized and studied. New dinuclear CN-palladacycles and their mononuclear triphenylphosphine derivatives were obtained. It was shown that ortho-palladation of terpene diphenylmethylimines produced pure stereoisomers.

引用

页码：648 / 651

页数：4

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