Synthesis and crystal structure of [Na3(H2O)6,5(EtOH)][PhSnS3]•3EtOH

被引：0
|
作者：
Hanser, R [1 ]
Merzweiler, K [1 ]
机构：
[1] Univ Halle Wittenberg, Inst Anorgan Chem, D-06120 Halle, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1998年 / 624卷 / 01期
关键词：
tin; sulfur; crystal structure;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ph4Sn4S6 reacts with Na2S . 5H(2)O in aqueous acetone to form Na-3[PhSnS3]. Recrystallization of the crude product from ethanol leads to colourless needles of [Na-3(H2O)(6,5)(EtOH)][PhSnS3]. 3EtOH 1. The crystal structure of 1 was determined by X-ray diffraction. 1 consists of[PhSnS3](3-) anions and sodium cations which are coordinated by water, ethanol and sulfur atoms of the [PhSnS3](3-) anions. The [PhSnS3](3-) anion contains a tin atom which is coordinated nearly tetrahedrally by a phenyl group and three sulfur atoms. The Sn-S bonds are 237,4(2)-238,4(2) pm.
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页码：10 / 12
页数：3
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