Synthesis and crystal structure of [Na3(H2O)6,5(EtOH)][PhSnS3]•3EtOH

被引：0

作者：

Hanser, R ^{[1
]}

Merzweiler, K ^{[1
]}

机构：

[1] Univ Halle Wittenberg, Inst Anorgan Chem, D-06120 Halle, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1998年 / 624卷 / 01期

关键词：

tin; sulfur; crystal structure;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ph4Sn4S6 reacts with Na2S . 5H(2)O in aqueous acetone to form Na-3[PhSnS3]. Recrystallization of the crude product from ethanol leads to colourless needles of [Na-3(H2O)(6,5)(EtOH)][PhSnS3]. 3EtOH 1. The crystal structure of 1 was determined by X-ray diffraction. 1 consists of[PhSnS3](3-) anions and sodium cations which are coordinated by water, ethanol and sulfur atoms of the [PhSnS3](3-) anions. The [PhSnS3](3-) anion contains a tin atom which is coordinated nearly tetrahedrally by a phenyl group and three sulfur atoms. The Sn-S bonds are 237,4(2)-238,4(2) pm.

引用

页码：10 / 12

页数：3

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