Stereoselective synthesis of (+)-boronolide

被引：24
|
作者：
Naidu, SV [1 ]
Gupta, P [1 ]
Kumar, P [1 ]
机构：
[1] Natl Chem Lab, Div Organ Chem Technol, Pune 411008, Maharashtra, India
来源：
TETRAHEDRON LETTERS | 2005年 / 46卷 / 12期
关键词：
D O I：
10.1016/j.tetlet.2005.01.120
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient enantio- and stereocontrolled total synthesis of (+)-boronolide from valeralclehyde is described. The key steps include a Sharpless asymmetric dihydroxylation, a chelation controlled Grignard reaction followed by Sharpless asymmetric epoxidation and a ring closing metathesis. (C) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2129 / 2131
页数：3
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