Stereoselective synthesis of (+)-boronolide

被引：24

作者：

Naidu, SV ^{[1
]}

Gupta, P ^{[1
]}

Kumar, P ^{[1
]}

机构：

[1] Natl Chem Lab, Div Organ Chem Technol, Pune 411008, Maharashtra, India

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 12期

关键词：

D O I：

10.1016/j.tetlet.2005.01.120

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient enantio- and stereocontrolled total synthesis of (+)-boronolide from valeralclehyde is described. The key steps include a Sharpless asymmetric dihydroxylation, a chelation controlled Grignard reaction followed by Sharpless asymmetric epoxidation and a ring closing metathesis. (C) 2005 Elsevier Ltd. All rights reserved.

引用

页码：2129 / 2131

页数：3

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