A novel organic-inorganic hybrid based on a dinuclear copper complex supported on a keggin polyoxometalate

被引：149

作者：

Reinoso, S ^{[1
]}

Vitoria, P ^{[1
]}

Lezama, L ^{[1
]}

Luque, A ^{[1
]}

Gutiérrez-Zorrilla, JM ^{[1
]}

机构：

[1] Univ Basque Country, Fac Ciencias, Dept Quim Inorgan, E-48080 Bilbao, Spain

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 12期

关键词：

D O I：

10.1021/ic034203a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The autoassembly process of copper-oxalate dimers and Keggin type polyoxometalates leads to the first example of a new family of organic-inorganic hybrids, K-14[{Cu-2(bpy)(2)(mu-ox)}{SiW11O39Cu(H2O)}](2)[SiW11O39Cu(H2O)].similar to55H(2)O. This compound crystallizes in the monoclinic space group C2/m, a = 37.932(6) Angstrom, b = 21.303(3) Angstrom, c = 12.546(2) Angstrom, beta = 106.16(1)degrees, Z = 2. The crystal structure reveals the presence of a polymeric hybrid built up of alternating dimer and polyoxometalate entities.

引用

页码：3709 / 3711

页数：3

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