A novel organic-inorganic hybrid based on a dinuclear copper complex supported on a keggin polyoxometalate

被引：149
|
作者：
Reinoso, S [1 ]
Vitoria, P [1 ]
Lezama, L [1 ]
Luque, A [1 ]
Gutiérrez-Zorrilla, JM [1 ]
机构：
[1] Univ Basque Country, Fac Ciencias, Dept Quim Inorgan, E-48080 Bilbao, Spain
来源：
INORGANIC CHEMISTRY | 2003年 / 42卷 / 12期
关键词：
D O I：
10.1021/ic034203a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The autoassembly process of copper-oxalate dimers and Keggin type polyoxometalates leads to the first example of a new family of organic-inorganic hybrids, K-14[{Cu-2(bpy)(2)(mu-ox)}{SiW11O39Cu(H2O)}](2)[SiW11O39Cu(H2O)].similar to55H(2)O. This compound crystallizes in the monoclinic space group C2/m, a = 37.932(6) Angstrom, b = 21.303(3) Angstrom, c = 12.546(2) Angstrom, beta = 106.16(1)degrees, Z = 2. The crystal structure reveals the presence of a polymeric hybrid built up of alternating dimer and polyoxometalate entities.
引用
收藏
页码：3709 / 3711
页数：3
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