Thermodynamic and morphological characterization of Turing patterns in non-isothermal reaction-diffusion systems

被引:11
|
作者
Serna, Horacio [1 ]
Munuzuri, Alberto P. [2 ]
Barragan, Daniel [1 ]
机构
[1] Univ Nacl Colombia, Dept Chem, Grp Calorimetry & Irreversible Proc Thermodynam, Fac Sci, Campus El Volador,Bloque 16,Calle 59A 63-20, Medellin, Colombia
[2] Univ Santiago de Compostela, Dept Phys, Grp Nonlinear Phys, Santiago, Spain
关键词
MINKOWSKI FUNCTIONALS; ENTROPY PRODUCTION; OSCILLATIONS; TEMPERATURE;
D O I
10.1039/c7cp00543a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effect of temperature on the bifurcation diagram and Turing instability domain under non isothermal conditions is studied in the reversible Gray-Scott model. After adding the energy balance to the cubic autocatalytic model, the thermostat temperature and heat transfer coefficient are used as control parameters in the Turing pattern formation. The patterns obtained in the domain of the thermal parameter are characterized by quantifying the overall entropy generation rate and two topological indices; Shannon entropy and Minkowski functionals. The results show that it is possible to induce transitions between Turing patterns of different morphologies by regulating the temperature, and that these transitions take place at a lower entropy generation value compared to other parameters, such as kinetic constants and reactant fluxes. Finally, a correlation between entropy generation and topological indices shows that a difference between direct and inverse patterns is mainly morphological and not energetic.
引用
收藏
页码:14401 / 14411
页数:11
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