Aquanitrilotris(methylenephosphonato)bis(dimercury(I)) Hydrate, [(Hg2)2(H2O) N(CH2PO3)3H2]•H2O: Synthesis, Structure, and Properties

被引：1

作者：

Somov, N. V. ^{[1
]}

Chausov, F. F. ^{[2
,3
]}

Zakirova, R. M. ^{[3
]}

Shumilova, M. A. ^{[4
]}

Aleksandrov, V. A. ^{[4
]}

Petrov, V. G. ^{[4
]}

机构：

[1] NI Lobachevskii State Univ, Nizhnii Novgorod, Russia

[2] Russian Acad Sci, Ural Branch, Physical Tech Inst, Izhevsk, Russia

[3] Udmurt State Univ, Izhevsk, Russia

[4] Russian Acad Sci, Inst Mech, Ural Branch, Izhevsk, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2016年 / 42卷 / 01期

关键词：

VIBRATIONAL-SPECTRA; CRYSTAL-STRUCTURE; THERMAL-BEHAVIOR; COMPLEXES; PHOSPHONATES; MERCURATION; CHEMISTRY; PHOSPHATE;

D O I：

10.1134/S107032841601005X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A reaction of dimercury(I) dinitrate with nitrilotris(methylenephosphonic acid), N(CH2PO3)(3)H-6, gave the complex [(Hg-2)(2)(H2O){N(CH2PO3)(3)H-2}] center dot H2O. The crystals of the complex are triclinic, space group P (1) over bar Z = 2, a = 8.3436(3), b = 9.0744(3), c = 11.1124(4) angstrom, a = 91.875(3)degrees, beta= 104.452(3)degrees, gamma = 92.195(3)degrees (CIF file CCDC no. 1051860). The atoms of either dimercury cation are coordinated differently, making up a distorted tetrahedron and a distorted trigonal bipyramid. The ligand is coordinated to the Hg atoms through seven donor atoms: six (out of nine) O atoms and a N atom. The coordination involves the formation of chelate rings: two four-membered, three five-membered, a six-membered, and an eight-membered ring.

引用

页码：37 / 43

页数：7

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